Organic Syntheses: An Annual Publication of Satisfactory by Charles C. (Editor-in-Chief) Price

By Charles C. (Editor-in-Chief) Price

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Im Gift der Feuerameise Solenapsis saevissima aufgefundenen Solenopsine A, B und C (55) sowie die Dehydrosolenopsine B und C (55a) genannt, deren Struktur durch Synthese bestätigt werden konnte (204). Es sind die ersten alkylierten Piperidinderivate, die in einem tierischen Gift nachgewiesen worden sind. Die absolute Konfiguration ist noch unbekannt, möglicherweise besitzen (55) und (55a) auch die spiegelbildliche Anordnung der Substituenten. Die Doppelbindung in der Seitenkette der Dehydrosolenopsine B und C ist cis-ständig.

T. 0HASHI, :'li. YoXE:\IITSt: ancl S. YASUDA: Constitucnts of Suphar japonicum. XXI\". Structure of a New Alkaloid, Anhyclronupharamine. Yakugaku Zasshi 87, rog~ (1967) ~Chem . ~bstr. 68, 2912 (1968)]. ARNDT, R. R. ancl L. M. Du PLEssrs: The Alkaloids of Coclidium fourcadci. J. S. Afr. Chem. Inst. 21. 5~ (1968) ~Chem. Abstr. 70, ~3~1f (1969)]. ARTHUR, H. R. ancl R. P. K. \lkaloid from Isolama longiflora. J. Chem. Soc. (London) 1963, 750. AsLANOV, X. , S. Z. \. S. SADYKOV: Chemical Stuclies of the Anabasis aphylla Seccls.

44· 584 (1957)· I39· HAssE, K. und H. MAISACK: ,;Jl-Pyrrolin und LI 1 -Piperidein aus Putrescin und Cadaverin durch enzymatische Oxydation. Naturwiss. 42, 627 (1955). I40. : Isolation of Pipecolinic Acid from Phasealus angularis. Sei. Pap. Coll. Gen. , Univ. Tokyo 17, 219 (1967) [Chem. Abstr. 70, 882i (1969)]. I4I. HEGARTY, M. : The Isolation and Identification of s-Hydroxypiperidine-zcarboxylic Acid from Leucaena glauca Benth. Austral. J. Chem. 10, 484 (1957). I42. HIGHET, R. : Alkaloids of Cassia Species.

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