Content material: development within the chemistry of polyconjugated structures / B.E. Bavydov and B.A. Krenstel -- Behaviour of furan derivatives in polymerization reactions / A. Gandini -- Chemical adjustments of fibre forming polymers and copolymers of acrylonitrile / G.A. Gabrielyan and Z.A. Rogovin -- man made polyelectrolytes as types of nucleic acids and esterases / by means of T. Okubo and N. Ise
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Extra info for Intrinsic Molecular Mobility And Toughness Of Polymers
Dynamic Mechanical Analysis . . . . . . . . . . 13 C NMR Measurements in the DGEBA/HMDA/AP19 Network NMR Location of the Antiplasticiser in the Epoxy Network . Conclusion on Motions in Antiplasticised Epoxy Networks . . Conclusion on the Motions Involved in the Glassy State Transitions in Aryl-aliphatic Epoxy Resins . . . . . . . . . . . . . 130 131 134 140 . . . . . . . . . . . . . . . . . . 144 145 146 148 152 153 . . . 2 . . . . . . . . .
On the one hand important properties of thermoplastic polymers (low processing temperatures, ductility, increased toughness) depend on it. On the other hand without exception all damage mechanisms, which limit strength and durability, are related to molecular motions. A micro-mechanical model of an entangled physical network has been presented and used to point out the intimate interpenetration of chain molecules in the solid state, to identify the roles of the four major disintegrating mechanisms chain scission, segmental slip, disentanglement and ﬂow in mechanical loading, and to discuss the effect of time and the importance of hydrostatic tensile stresses.
Wilding MA, Ward IM (1978) Polymer 19:969 45. Plummer CJG (2004) Adv in Polymer Si 169:75 46. Damen J, Schramm D, Anderson K (2004) Plastic Pipes XII, Session 10b The Effect of Time on Crazing and Fracture 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. 57. 58. 59. 60. 61. 62. 63. 64. 65. 66. 67. 68. 69. 70. 71. 72. 73. 74. 33 da Andrade ENC (1910) Proc Royal Soc London 84:1 Findley WN (1987) Polym Eng Sci 27:582 Schapery RA (1997) Mechanics of Time-Dependent Materials 1:209 Gregory A, Vogel D, Béguelin PH, Gensler R, Kausch H-H (1999) Mechanics of TimeDependent Materials 3:71 Pilz G, Lang RW (2001) Proceedings of Plastics Pipes XI, p 903 Niklas H, Kausch von Schmeling HH (1963) Kunststoffe 53:886 Janson LE, Bergstrom G, Backman M, Blomster T, Plastic Pipes XII, Session 10b Starke JU, Schulze G, Michler GH (1997) Acta Polymer 48:92 Kambour RP (1968) Appl Polymer Symposia 7:215 Rabinowitz S, Beardmore P (1969) CRC Critical Reviews 1:1 Kausch H-H (ed) (1983) Crazing in Polymers Advances in Polymer Science, 52/53.