Biothiols by Packer L.

By Packer L.

This specific, cutting-edge reference offers an in depth account of the molecular mechanisms underlying the a number of capabilities of biothiols-emphasizing the organic and medical implications of interactions among oxidants and biothiols.

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Reactions of Special Radicals" (Z. B. ), p. 133. CRC Press, Boca Raton, Florida, 1988. 14 p. Wardman, in "Glutathione Conjugation. Mechanisms and Biological Significance" (H. Sies and B. ), p. 43. Academic Press, London, 1988. -D. Asmus, this series, Vol. 186, p. 168. 16 B. C. Gilbert, in "Sulfur-Centered Reactive Intermediates in Chemistry and Biology" (C. -D. ), p. 135. Plenum, New York, 1990. 17 D. A. Armstrong, in "Sulfur-Centered Reactive Intermediates in Chemistry and Biology" (C. -D. ), p.

Pharmacol. 35, 21 (1986). 36 R. P. Mason, Free Radicals Biol. 5, 161 (1982). 37 T. E. Eling, R. P. Mason, and K. Sivarajah, J. Biol. Chem. 260, 1601 (1985). 38 L. G. Forni, V. O. Mora-Arellano, J. E. Packer, and R. L. Willson, J. Chem. , Perkin Trans. 2, 1579 (1988). 39 B. C. Gilbert, in "Sulfur-Centered Reactive Intermediates in Chemistry and Biology" (C. -D. ), p. 135. Plenum, New York, 1990. 4o M. D. Sevilla, D. Becker, and M. Yan, Int. J. Radiat. Biol. 57, 65 (1990). ) have been subject to extensive investigation whereas ESR spectra of the thiyl radical itself are generally hardly observable or difficult to analyze.

Biophys. 292, 456 (1992). 6 p. O'Neill, Radiar Res. 96, 198 (1983). METHODS IN ENZYMOLOGY, VOL. 251 Copyright © 1995 by Academic Press, Inc. All rights of reproduction in any form reserved. 32 THIYL RADICALS [31 Xenobiotic radicals produced by one-electron oxidation of drugs are often reactive toward thiols. Examples include aromatic amines, phenothiazines, or phenols. 7-11 The "repair" of a phenothiazine (PZ) radical cation by thiols is representative: P Z -+ + R S H ~ P Z + RS- + H + (3) Equation (3) contrasts with Eq.

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